Ruthenium-catalyzed nucleophilic fluorination of halobenzenes.
نویسندگان
چکیده
The first π-coordination-catalyzed nucleophilic fluorination of unactivated aryl halides has been demonstrated. Chlorobenzene reacts with alkali metal fluorides (CsF, KF) in the presence of a Cp*Ru catalyst at 120-180 °C to give fluorobenzene.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 70 شماره
صفحات -
تاریخ انتشار 2015